I found this in Varien_Data_Form_Element_Select which generates the select option html
$fieldset->addField( 'sample', 'select', array( 'label' => 'Sample Dropdown', 'name' => 'sample', 'class' => '', 'note' => '', 'style' => '', 'values'=> array(1=>'Yes', 2=>'No') ) );
Find: with in same form file
$form->setValues($values);
Add line before:
// add this line just before setValues() $values['sample'] = array(2);
if your form have no setValues() function just add value in addField like this
$fieldset->addField( 'sample', 'select', array( 'label' => 'Sample Dropdown', 'name' => 'sample', 'class' => '', 'note' => '', 'style' => '', 'values'=> array(1=>'Yes', 2=>'No') 'value'=> array(2) ) );
option with value 2 will be selected.